首页> 外文会议>NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials >INVESTIGATION OF THE MICROSTRUCTURE OF METAL CATALYZED CYCLOPENTENE CO-NORBORNENE POLYMERS BY SPECTRAL METHODS
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INVESTIGATION OF THE MICROSTRUCTURE OF METAL CATALYZED CYCLOPENTENE CO-NORBORNENE POLYMERS BY SPECTRAL METHODS

机译:光谱法研究金属催化环戊烯辅冰片烯聚合物的微观结构

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摘要

For the first time, cyclopentene (CPE) has been copolymerized with the strained cycloolefin norbornene (NBE) using catalytic amounts of the electrochemi-cally prepared metathesis catalyst. The microstructure of polymers was determined by ~1H NMR and ~(13)C NMR spectroscopy. The polymers were also characterized by differential scanning calorimetry and gel permeation chromatography (GPC) techniques.
机译:首次,使用催化量的电化学 - 电石制备的复分解催化剂,所述环戊烯(CPE)与应变的环烯烃降冰片烯(NBE)共聚。聚合物的微观结构由〜1H NMR和〜(13)C NMR光谱法测定。该聚合物的特征还通过差示扫描量热法和凝胶渗透色谱(GPC)技术。

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