SYNTHESIS AND CHARACTERIZATION OF 3,4,5-TRIAMINO-1,2,4-TRIAZOLIUM 5'-NITROTETRAZOLATE

摘要

3,4,5-Triamino-1,2,4-triazolium 5'-nitrotetrazolate (2) was synthesized in high yield from 3,4,5- Triamino-1,2,4-triazole (Guanazine) (1) and ammonium 5-nitrotetrazolate. The new compound (2) was characterized using vibrational (IR and Raman) and multinuclear AMR spectroscopy (~1H, ~13C, ~15N), elemental analysis and single crystal X-ray diffraction. 3,4,5-Triamino-I,2,4- triazolium 5'-nitrotetrazolate (2) represents a new example of an energetic material which contains a triazole and tetrazole based cation and anion. Some explosive properties were determined and the experimental values were compared to the theoratical ones.