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Thermoelectric Properties of FeSi2 using Rutile-Titanium Oxide

机译:使用金红石氧化钛的FeSi2热电性能

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Energy Transformation by temperature difference is performed using thermoelectric semiconductor and is crucial issue to employ exhaust heat in our daily life. A metal oxide has been popular now besides metal compound like Bi_2Te_3. Unfortunately, an oxide seems to be low electrical conductivity in general. However, an oxide has high thermoelectric power (Seebeck coefficient) and relatively low thermal conductivity. We study rutile-TiO_2 to decrease electrical resistivity during maintaining higher Seebeck coefficient and lower thermal conductivity. Electrical resistivity of 1 wt percent added-TiO_2 was 2.7 X 10~(-5) OMEGA m around 700K meaning 45 percent reduction. As a result, power factor for the specimen was the highest which was 1.4 X 10~(-3)around 700K, 1.4 times larger than the none-added specimen (standard). The effective charge of Fe was 1.88 and Ti was 2.42 ,meaning that the electrons seemed to move to Fe. Transport coefficient of thermoelectricity was also discussed associating with Onsager's equation
机译:使用热电半导体进行温度差异的能量变换,并且在我们的日常生活中使用废热至关重要的问题。除了像金属化合物之外,金属氧化物现在已经流行了Bi_2Te_3。不幸的是,氧化物似乎通常是低电导率。然而,氧化物具有高热电动力(Seebeck系数)和相对低的导热率。我们研究了金红石-TIO_2,以降低在保持更高的塞贝克系数和较低的导热性期间的电阻率。 1wt%的电阻率加入-TiO_2为2.7×10〜(-5)omega m左右700k,含有45%的减少。结果,标本的功率因数是大约700k的1.4×10〜(-3)的功率因数,比无添加样品大的1.4倍(标准)。 Fe的有效费用为1.88,Ti为2.42,这意味着电子似乎移动到Fe。还讨论了热电系数与OnSager的等式相关联

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