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EVALUATION OF WHITE BENTONITE MODIFIED BY ACID ATTACK

机译:酸攻击修饰白膨润土的评价

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For industrial use, the smectite clays must be cleared of impurities, usually obtained by acid modification, using a high concentration solution of inorganic acid at temperatures under boiling point. In the present paper, a sample of white bentonite from Paraiba, Brazil, was modified by hydrochloric acid under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, acid solution/clay ratio of lg/10mL). The puipose of these attacks is to reduce the concentration of impurities with minimal change in the clay minerals structure. The modified samples were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Cation Exchange Capacity (CEC), Stereomicroscopy, Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Detector (EDS). Thus, this modified bentonite tends to be a good economic and environmental alternative in manufacturing of products with high added value such as cosmetics and polymer/clay nanocomposites.
机译:对于工业用途,必须在沸点下的温度下使用高浓度的无机酸溶液清除通常通过酸改性获得的杂质的杂质。在本文中,在中等条件下由盐酸(90℃,1,6,12,18和24小时的盐酸修饰的白色膨润土样品在紧密反应器中,浓缩水溶液的浓度盐酸1.5米,酸溶液/粘土比Lg / 10ml)。这些攻击的脱脂剂是降低粘土矿物质结构中最小变化的杂质的浓度。通过X射线衍射(XRD),X射线荧光(XRF),阳离子交换能力(CEC),立体镜检查,扫描电子显微镜(SEM)和能量分散X射线检测器(EDS)进行了修饰的样品。因此,这种改性膨润土往往是制造具有高附加值的产品的良好的经济和环境替代品,例如化妆品和聚合物/粘土纳米复合材料。

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