Influences of Calcination Ambiences on Phase Composition and high Temperature Oxidation Resistance Property of Ceramic Coatings on Ti-6Al-4V Alloy by Micro-plasma Oxidation

摘要

Compound ceramic coatings with the main crystalline of Al_2TiO_5 (as-coated samples) were prepared on Ti-6Al-4V alloy by pulsed bi-polar micro-plasma oxidation (MPO) in NaAlO_2 solution. The coated samples were calcined in Ar and air at 1000°C, respectively. The phase composition, morphology and element content of the coatings were investigated by XRD, SEM and XRF. The samples treated in Ar and the as-coated ones were calcined in air at 1000°C to study the oxidation resistance of the samples. The results showed that Al_2TiO_5 decomposed and transformed into corundum and rutile TiO_2 during the high temperature calcination. Al_2TiO_5 decomposed very quickly in air and the proportion of Al_2O_3 to TiO_2 was 44:55 after a complete decomposition. On the contrary, Al_2TiO_5 decomposed very slowly in argon with the final proportion of Al_2O_3 to TiO_2 of 81:18 on the coating surface. The morphology of the ceramic coatings after the calcination was also different. The coatings calcined in argon were fined: the grains and pores were smaller than those of the coatings calcined in air. The weight gains of both coatings changed in the form of parabola law, and the weight gains of the coated samples treated in argon were comparatively lower than that of the as-coated samples. During the high temperature calcination, the samples treated in argon cannot distort easily, compared with the as-coated ones.