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Cerium and lanthanum oxide-based sorbents for regenerative hot reformate gas desulfurization

机译:基于氧化铈和镧系氧化物的吸附剂,用于再生热重整物气脱硫

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摘要

Desulfurization of the hot reformate gas produced by catalytic partial oxidation or autothermal reforming of heavy fuels, such as JP-8, is required prior to using the gas in a solid oxide fuel cell (SOFC). Development of suitable sorbent materials involves the choice of sorbents with favorable sulfidation equilibria, good kinetics, and high structural stability and regenerability at the SOFC operating temperatures (650-800°C). A major barrier is the gradual loss of sorbent performance in cyclic sulfidation and regeneration at such high temperatures.
机译:在使用固体氧化物燃料电池(SOFC)中的气体之前,需要通过催化部分氧化或重型燃料(如JP-8)的热重整物的热重整液的脱硫。合适的吸附剂材料的开发涉及在SOFC工作温度(650-800°C)中选择具有有利硫化平衡,良好动力学和高结构稳定性和再生性的吸附剂。主要屏障是在这种高温下循环硫化和再生中的吸附剂性能逐渐丧失。

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