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Synthesis and Screening of Materials Libraries of Buried Compound Semiconductors by Ion Beam Implantation

机译:离子束植入埋藏半导体材料文库的合成及筛选

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A combinatorial approach was employed to ion beam synthesis and optical analysis of buried II-VI compound CdSe semiconductor nanocrystals. Typically standard ion implantation setups are designed in a way to create a laterally homogenous dose distribution of the implanted ion species. In order to achieve intentional lateral variations of the implanted doses a special implanler endstation was constructed. Computer controlled apertures in front of the wafer cover up in succession parts of a 4 in. wafer, so that a lateral pattern of distinct dose combinations of the implanted elements Cd and Se was generated. The obtained materials library consists of 1:1 stoichiometric, but also off-stoichiometric dose ratios. After implantation the wafers passed through a rapid thermal heat treatment, where the implanted material forms buried semiconductor nanocrystals. Photoluminescence spectra of the elements of the materials library were screened in rapid succession in an optical cryostat into which the whole wafer was mounted and cooled down. The obtained spectra were compared and key-parameters determined which control the photoluminescence properties. In this contribution will be shown, that slight variations of the dose ratio significantly alter the optical properties and that new efficient photoluminescent materials and processing parameters can be found. In this way, also other complex interdependencies of physical and chemical parameters in the field of multiple element ion beam implantation might be efficiently investigated.
机译:用于离子束合成和掩埋II-VI复合CDSE半导体纳米晶体离子束合成和光学分析的组合方法。通常,标准的离子注入设置被设计成以植入离子物种的横向均匀剂量分布的方式设计。为了实现植入剂量的有意的横向变化,构建了特殊的植入物圆顶。晶片前面的计算机控制孔在晶片的连续部分中覆盖。晶片,使得产生植入元件CD和Se的不同剂量组合的横向图案。所获得的材料库由1:1化学计量,但也是脱离化学计量的剂量比。在植入后,晶片通过快速的热热处理,其中植入材料形成掩埋半导体纳米晶体。在光学低温恒温器中快速地筛选材料库的光致发光光谱,将整个晶片安装并冷却到下方。比较所获得的光谱和测定的键参数,其控制光致发光性质。在该贡献中,将显示,剂量比的轻微变化显着改变光学性质,并且可以找到新的高效光致发光材料和加工参数。以这种方式,也可以有效地研究多元件离子束注入领域的物理和化学参数的其他复杂相互依赖性。

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