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Synthesis and property evaluation of a new co-polymer for polymer flooding in high salinity high temperature reservoirs

机译:高盐度高温储层聚合物洪水新共聚物的合成与性质评价

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Polymer flooding Is one of most cost-effective methods to significantly improve oil recovery for many mature oilfields. However, conventional polymer can not be applied In high temperature and high salinity formation due to their low tolerance to high temperature and high salinity. This paper will introduce the systhesis process and the evaluation results for a new terpolymer which has been successfully synthesized in lab and successfully applied In high temperature and high salinity reservoirs.The terpolymer, named NKP-85, was successfully synthesized from acrylamlde (AM), a small amount of a hydrophobic monomer N-dodecyl acrylamlde (AMC12) and a polar monomer 2-Acrylamldo-2-methyl-propanesulfonlc add (AMPS) via mlcellar polymerization in water. The effect of initiation temperature and functional Initiator (MP) concentration on the new terpolymer molecular weight has been studied. The performance of the synthesized terpolymer was evaluated according to their molecular weight, salt resistance, thermal stability and their ability to Improve oil recovery over water flooding. Results show that the terpolymer has the best performance at an optimized Initiation temperature of 9°C and a concentration of MP of 150 mg/L. The optimized tempolymer has a molecular weight of 22,000,000 and Its 1,500 ppm solution can still keep a viscosity of 18.7 mpa.s In 32,000 formation water salinity and 85°C within one month, which is significantly better than other commercial available products. The shear rate effect on the polymer viscosity will also be reported.The polymer will have a broad application In polymer flooding since it can be used at severe temperature and high salt condition.
机译:聚合物洪水是最具成本效益的方法之一,可显着提高许多成熟油田的石油回收。然而,由于其对高温和高盐度的低耐受性,常规聚合物不能在高温和高盐度形成中施加。本文将介绍Systhesis工艺,并在实验室成功合成的新三元共聚物的评价结果​​,并成功地应用于高温和高盐储存器。从丙烯酰胺(AM)成功地合成了NKP-85的萜酯,少量疏水性单体N-十二烷基丙烯酰基(AMC12)和极性单体2-丙烯酰基-2-甲基 - Propanesulfonlc通过Mlcellar聚合在水中添加(AMPS)。研究了启动温度和功能引发剂(MP)浓度对新的三元共聚物分子量的影响。根据其分子量,耐盐,热稳定性评价合成的三元共聚物的性能及其改善水洪水溢油的能力。结果表明,三元共聚物在9℃的优化起始温度下具有最佳性能,浓度为150mg / L.优化的细聚合物的分子量为22,000,000,其1,500ppm溶液仍然可以保持18.7MPa的粘度为18.7MPa。在一个月内以85°C为85°C,这明显优于其他商业可用产品。还将报道对聚合物粘度的剪切速率效应。聚合物将在聚合物洪水中具有广泛的应用,因为它可以在严重的温度和高盐条件下使用。

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