The synthesis of some poly(bisphenol-A)carbonates (PCs) containing hydrophilic porphyrin units as end groups, by thermal treatment of commercial PC and 5,10,15-tri{p["-methoxy-poly(oxyethylene)]phenyl}20(p-hydroxy phenyl)porphyrin (I) blends, is reported. A suitable choice of reaction temperature, molar composition and reaction time, allowing the extent of the outer-inner transesterification reactions, leads to a gradual insertion of porphyrin units in the polymer chains. The composition of the obtained materials was inferred by GPC and MALDI-TOF mass spectrometric analysis.
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机译：通过热处理商业PC的热处理和5,10,15-Tri {P [“ - 甲氧基 - 聚（氧乙烯）]苯基合成含有亲水性卟啉单位的聚（双酚-A）碳酸酯（PCS）作为末端组。 - 甲氧基 - 聚（氧乙烯）]苯基} 20(p-hydroxy phenyl)porphyrin (I) blends, is reported. A suitable choice of reaction temperature, molar composition and reaction time, allowing the extent of the outer-inner transesterification reactions, leads to a gradual insertion of porphyrin units in the聚合物链。通过GPC和MALDI-TOF质谱分析推断所得材料的组成。
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