LITHIUM INTERCALATION INTO GRAPHITE: PREDICTING DIFFUSION COEFFICIENT AND EXCHANGE CURRENT FROM THE DISCHARGE CURVES -

摘要

A simple theoretical model is presented to simulate the galvanostatic discharge behavior of the Ni-composite graphite electrode. The discharge profiles predicted by using a constant diffusion coefficient (CDC) and by a varied diffusion coefficient (VDC) are compared in this paper. The results show that the varied diffusion coefficient (VDC) model can be simplified to the constant diffusion coefficient (CDC) for discharge rates less than 2C for a 5 μm particle. Also, an approximate analytical solution is presented for VDC model, which is found to be valid for discharge rates up to 6C. Exchange current and diffusion coefficient for the lithium-diffusion are predicted.