CORROSION STUDIES OF HIGH AND LOW PRESSURE COMPRESSORS BLADES OF A GAS TURBINE

摘要

This work presents preliminary results of corrosion studies for three blades, one of the low pressure compressor and two of two different stages of the high pressure compressor of a gas turbine, which has been operating for 5,000 hours. Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), X-ray diffraction (XRD), Electrochemical Impedance Spectroscopy (EIS) in aqueous solution containing chloride, and Atomic Absorption Spectrometry (AAS) were used to characterize the blades surfaces. The SEM and EDS results showed that the homogeneity and amount of contaminants, such as sodium, potassium, calcium, magnesium, chloride and sulphur are bigger in the high pressure compressor blade surfaces than in the low pressure compressor blade surface. The EIS results showed that the degradation process in turbine compressor blades increases with the temperature and pressure increase inside the compressors and depends of the blade composition. The low pressure compressor blade, which was made of a Ti base superalloy exhibited smaller corrosion resistance (smallest charge transfer resistance value (R_(ct))) than the two high pressure compressor blades, which were made of a Fe base superalloy. However, despite of its lower resistance to corrosion, after 5,000 hours of service, the low pressure compressor blade did not present pitting corrosion while the high pressure compressor blades did.