Preparation of isolated iron species in ZSM-5 for high selectivity alcohol formation from lower alkanes under mild conditions (PPT)

摘要

"New type" ofFe species observed 1. Isolated, Oxygen only eoordination sphere 2. Benefieial effect on alcohol selectivity for both ethane and methane 3. Reusable, thus non-transient effect 4. Enhanced productivity in direct route to ethanol from ethane implies possibility direct route for methanol, involving O2 possibly