CNT supported iron catalysts, an unsupported Fe/Cu/K/SiO2 FT catalysts was prepared by the Cosmos method. Using this method, a uniform crystallite size distribution between 2 to 4 nm can be obtained. This new catalyst preparation method was compared with published studies [10, 11, 12] and shows promising selectivity and activity. This method is much faster and requires fewer preparation steps compared to the other methods. An active catalyst with low selectivity to methane was obtained by using CNT as support. The washing step effects on the rates and distribution of the products. Higher water gas shift activity and lower methane selectivity was resulted on washed CNT/Fe/K/Cu.
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机译:CNT负载的铁催化剂,通过宇宙方法制备不支持的Fe / Cu / K / SiO 2 FT催化剂。使用该方法,可以获得2至4nm之间的均匀微晶尺寸分布。将这种新的催化剂制备方法与公开的研究进行了比较[10,11,12]并显示有前途的选择性和活性。与其他方法相比,这种方法更快,需要更少的准备步骤。通过使用CNT作为载体获得具有较低选择性甲烷的活性催化剂。洗涤步骤对产品的速率和分布的影响。在洗涤的CNT / Fe / K / Cu上导致较高的水换水活性和较低的甲烷选择性。
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