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Influence of crystalline TPUs on properties of polyurethane reactive hotmelts (HMPUR)

机译:结晶TPU对聚氨酯反应性Hotmelts(HMPUR)性能的影响

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The basic components in the production of HMPUR are polyols and diisocyanates: by reacting them, they produce polyurethane prepolymer. The free isocyanate groups of this polyurethane prepolymer react with ambient moisture, once this latter is applied. During the production process of HMPUR, the addition of crystalline thermoplastic polyurethanes (TPUs) with different molecular weights and chemical structures (PEARLBOND?), allow the adhesives makers to adjust several properties such as green strength, setting-time, open-time, viscosity and specific adhesion to different substrates, depending on the application requirements. A formulation based on a mixture of crystalline and amorphous polyester has been used for the evaluation of the action of the crystalline TPUs (PEARLBOND?). Once the mixture is homogenized, the polyurethane prepolymer is formed by adding 4,4-diphenyl-methane diisocyanate (MDI).The influence of the addition of the different PEARLBOND? types on the final properties of the HMPUR is evaluated, as well as the proportions to be used.
机译:HMPUR生产中的基本组分是多元醇和二异氰酸酯:通过使它们反应,它们产生聚氨酯预聚物。该聚氨酯预聚物的游离异氰酸酯基团与环境水分反应,一旦施加后者就会与环境湿气反应。在HMPUR的生产过程中,添加具有不同分子量和化学结构的结晶热塑性聚氨酯(TPU)(珠宝?),允许粘合剂制造商调整几种性能,如绿色强度,设定时间,开放时间,粘度根据应用要求,对不同基材的特定粘附性。基于结晶和无定形聚酯的混合物的制剂已被用于评价结晶TPU(珠宝→)的作用。一旦混合物均化,通过加入4,4-二苯基 - 甲烷二异氰酸酯(MDI)形成聚氨酯预聚物。添加不同珍珠素的影响?评估HMPUR的最终属性的类型,以及要使用的比例。

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