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Orientational relaxation and Brownian motion

机译:取向松弛和布朗运动

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The theory of Brownian motion was developed first by Einstein [1] for a single spherical particle immersed in a fluid and subjected to an external potential. Einstein realized that on a sufficiently slow time scale the observed random displacements of the particle can be described by a generalized diffusion equation. The particle momentum can be ignored, since it changes on a much faster time scale. Its probability distribution rapidly becomes nearly maxwellian, corresponding to the temperature of the fluid [2, 3]. Einstein's simple equation for a single particle was generalized by Smolu-chowski to the mutual diffusion of a pair of particles, interacting with a central potential [4]. He also considered the possibility of reaction between the two partners [5]. The modern theory of interacting Brownian particles is based on a generalized Smoluchowski equation for the probability distribution of the entire configuration of particles [6].
机译:布朗运动理论首先由Einstein [1]开发,用于浸入流体中并进行外部潜力的单个球形颗粒。爱因斯坦意识到,在足够慢的时间尺度上,通过广义扩散方程可以描述粒子的观察到的随机位移。粒子动量可以忽略,因为它更快地改变了更快的时间尺度。其概率分布迅速变为近千年人,对应于流体的温度[2,3]。爱因斯坦的单颗粒的简单方程由Smolu-Chowski推广到一对颗粒的相互扩散,与中心电位相互作用[4]。他还考虑了两位合作伙伴之间反应的可能性[5]。棕色颗粒的现代巧妙颗粒理论基于颗粒的整个配置的概率分布的广义斯莫克斯基公式[6]。

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