Pulse current electrodeposition of Sm-Co alloys from aqueous solutions has been studied at various peak current densities (PCD), solution temperatures, frequency (v), T_(on) and duty cycles (γ). A deposit content of 20 at %Sm was obtained at 25°C, higher than at 60°C in contrast to DC from bath of 1M Sm sulfamate, 0.05M Co sulfate, 0.15M glycine at pH6. This composition is sufficient to obtain the high performance permanent magnet intermetallics, Sm_2Co_(17) (10.5 at %) and SmCo_5 (16.7 at %), by appropriate heat treatment. Increased PCD, T_(on), γ and decreased solution temperature or frequency increased Sm deposit content and decreased current efficiency (CE). Magnetic saturation (M_s) decreased linearly with increased Sm deposit content as DC and sputtered films. Increased Sm content resulted in significant decrease in He_⊥but Hc‖ varied little.
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机译：在各种峰值电流密度（PCD），溶液温度，频率（V），T_（ON）和占空比（γ）下研究了来自水溶液的SM-CO合金的脉冲电流电沉积。在25℃下在25℃下获得20at％Sm的沉积含量，与来自1M Sm Sulfamate的浴，0.05m Co硫酸盐，0.15m在pH6的甘氨酸中的DC相比，高于60℃。该组合物足以通过适当的热处理获得高性能永磁体金属间金属间化合物，SM_2CO_（17）（10.5at％）和SMCO_5（16.7at％）。增加PCD，T_（ON），γ，溶液温度或频率降低，增加SM沉积含量并降低电流效率（CE）。磁饱和度（M_S）线性降低，随着DC和溅射膜的增加，SM沉积物含量增加。增加的SM含量导致HE_⊥BUTHC‖的显着降低变化。
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