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High Flux Nanofiltration Membranes Based on Interfacially Polymerized Polyamide on Nanofibrous Scaffolds

机译:基于酰基纤维支架界面聚合聚酰胺的高通量纳米滤膜

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Polymer membranes have been widely used at different levels of water purifications. Perhaps, the most challenging utilization of polymer membranes in water purification is desalination, where the chemical functionality and physical structures of the membranes (e.g. reverse osmosis (RO) membranes to treat brackish water or sea water) must be fine tuned to remove salt ions. With a slight reduction of the separation capability, nanofiltration (NF) membranes for water softening and removal of color, taste, odor and other small contaminants can be made. The thin film composite structure has been routinely adopted for fabrications of NF and RO membranes. One of the most common methods to prepare the selective top layer on support material is interfacial polymerization. The support material (e.g. ultrafiltration (UF) membranes with MWCO ~ 100k or higher) usually has only a relatively small surface area fraction as open pores (with pore sizes of a few nanometers), which impose severe flux restrictions. There have been several attempts to use highly porous supports as a substitute to replace the low flux UF membranes as support materials. One example is the anodiscTM type inorganic membranes for high flux NF applications. However, this technology is not so practical because of the difficulty in handling and high cost.
机译:聚合物膜已被广泛用于不同水平的水纯化。也许,在水净化中最具挑战性的聚合物膜利用是脱盐,其中膜的化学官能度和物理结构(例如,反渗透(RO)膜来治疗咸水或海水),必须进行微调以除去盐离子。通过略微减少分离能力,可以制造用于水软化和去除颜色,味道,气味和其他小污染物的纳滤(NF)膜。对于NF和RO膜的制造,已经常规采用薄膜复合结构。在载体材料上制备选择性顶层的最常用方法之一是界面聚合。支撑材料(例如,具有MWCO〜100k或更高或更高的超滤(UF)膜)通常仅具有相对小的表面积分数,作为开孔(具有几纳米的孔径),这施加严重的助焊剂限制。有几次尝试使用高度多孔的支撑件作为替代物,以将低通量UF膜替代为载体材料。一个例子是用于高通量NF应用的Anodisctm型无机膜。然而,由于难以处理和高成本,这种技术并不是那么实用。

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