Living copolymerization of propene and alpha-olefins with Me_2Si(eta~3-Flu)(~tBuN)TiMe_2-based catalysts

摘要

Development of group 4 metallocene catalysts enables us to synthesize a variety of stereoregular polyolefins and olefin-based copolymers.The success of metallocene catalysts has forced us to apply organometallic compounds for polymerization catalysts as so-called single-site catalysts from both the academic and industrial points of view.Those endeavors have resulted in various single-site catalysts for homo-and copolymerization of olefins and other hydrocarbon monmers.