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Interface-Induced Liquid Crystallinity for Bisphenol A Based Cyanate Ester Polymers

机译:双酚A基氰酸酯聚合物的界面诱导的液晶度

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Ansiotropic nanostructures are important elements of modern science and technology. Control of molecular order of structures is a powerful technique which gives the ability to tailor properties specific applications. For instance, the use of rod-like structures is improving the device characteristic of solar cells by alignment of electron carrying nanorods perpendicular to the electrode. Anisotorpic nanoparticles have also been used extensively to improve the performances of liquid crystalline display devices aside from influencing optical properties as well as electro-optical response, as they were used as alignment layers or mediators. Liquid-crystal phases of various type of materials have been identified in the suspensions (or dispersions) which due to their rigid-rod like shape and size such as V2O5 ribbons1a , tobacco mosaic viruse , inorganic nanorods , and carbon nanotubes . The unique characteristic of liquid crystallinity is the tendency of the molecules to align themselves with long-range order. For this purpose it is necessary to combine their anisotropy with mobility besides the solubility in a solvent . However, all these requirements add an extra step in order to make nanostructures applicable. Alternatively, we are introducing organic polycyanurate (PCE) anisotropic nanostructures having intrinsic liquid crystallinity. Furthermore, polycyanurate nanordos (PCEnr) and nanotubes (PCEnt) have residual cyanate ester functional groups along the tube/rod surface susceptible to further bioaffinity.
机译:厌氧纳米结构是现代科技的重要元素。结构的控制量是一种强大的技术,可以提供定制特性特定应用的能力。例如,使用棒状结构通过对准垂直于电极的电子承载纳米棒来改善太阳能电池的装置特性。同位于纳米颗粒也被广泛用于改善液晶显示装置的性能,除了影响光学性质以及电光响应,因为它们被用作取向层或介质。已经在悬浮液(或分散体)中鉴定了各种材料的液晶相,其由于它们的刚性棒状和尺寸,例如V2O5核磁共振,烟草镶嵌病毒,无机纳米棒和碳纳米管。液晶度的独特特征是分子与远程顺序对齐的趋势。为此目的,除了在溶剂中的溶解性外,必须将它们的各向异性与迁移性结合。但是,所有这些要求都增加了额外的步骤,以使纳米结构适用。或者,我们引入具有固有液晶度的有机多囊酸(PCE)各向异性纳米结构。此外,聚氰脲酸酯纳(PCENR)和纳米管(脊柱)沿管/棒表面具有易受进一步的生物分析性的残留的氰酸酯官能团。

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