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Adsorption, desorption and mobility characteristics of endosulfan and methamidophos in sandy-loam and clay

机译:含沙壤土和粘土中硫丹和甲氨基磷酸的吸附,解吸和迁移性特征

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Laboratory studies utilising radio-isotopic techniques were conducted to determine the adsorption, desorption and mobility of endosulfan and methamidophos in the sandy-loams of the Cameron Highlands and the clays of the Muda rice-growing areas. High Freundlich adsorption distribution coefficients [K ads(f)] for endosulfan (6.74 and 18.73) and low values for methamidophos (0.40 and 0.98) were obtained in the sandy-loams and clays respectively. The observed K_(oc) values for endosulfan were 351 (sandy-loam) and 1142 (clay), while K_(oc) values of 20.8 (sandy-loam) and 59.7 (clay) were obtained for methamidophos. Log K_(ow) of 0.40 and 1.25 were calculated for endosulfan and -1.96 and -1.21 for methamidophos in the sandy-loam and clay, respectively. Desorption was common to both pesticides, but the desorption capacity of methamidophos from each soil-type far exceeded that of endosulfan. Soil TLC and column studies showed that in both soils methamidophos was very mobile, while endosulfan had negligible mobility. The adsorption of both pesticides was not influenced by pesticide mixtures, but it was affected by temperature, pH and fertiliser (NPK).
机译:进行利用无线电同位素技术的实验室研究,以确定Cameron高地沙子壤土和牡丹稻草种植区的砂壤土中硫丹和甲氨基磷酸的吸附,解吸和迁移率。在砂土和粘土中,分别在含沙滤水和甲氨基磷酸(0.40和0.98)的高烧伤吸附分布系数[K ADS(F)]和甲氨酸(0.40和0.98)的低值。硫丹的观察到的K_(OC)值为351(砂质 - 壤土)和1142(粘土),而K_(OC)值为20.8(砂质壤土)和59.7(粘土)的甲胺磷。对于氨纶和-1.96和-1.96和-1.21,分别计算甲胺磷和粘土中的甲胺磷,分别计算0.40和1.25的Log K_(OW)。杀虫剂均常见的解吸,但从每种土壤型远远超过硫丹的甲胺磷的解吸能力。土壤TLC和柱研究表明,在两种土壤中,甲氨酸非常移动,而硫丹的迁移率可忽略不计。杀虫剂的吸附不受农药混合物的影响,但它受温度,pH和肥料(NPK)的影响。

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