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RELIABILITY OF CORROSION RATE MEASUREMENTS BY LINEAR POLARIZATION

机译:线性极化腐蚀速率测量的可靠性

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The purpose of the research was to study the reliability of corrosion rate measurements by linear polarization. Other electrochemical measurements such as corrosion potential and concrete resistivity were also studied. The measurement device used was Gecor6 /1/. Six reinforced concrete test slabs were prepared in the laboratory. Corrosion of the reinforcement was initiated by adding chloride to the concrete mix. The slabs were stored in conditioned climate rooms. The rate of corrosion, corrosion potential and concrete resistivity were monitored by periodical measurements of the slabs over 420 days. The scatter of the measurement results was studied. To determine the real rate of corrosion some of the concrete slabs were broken after the measurement period. The steel reinforcement was exposed and the amount of corrosion was evaluated both visually and by the gravimetric method. The observed amount of corrosion was compared with the theoretical amount of corrosion calculated on the basis of corrosion rate measurements. The depths of corrosion determined by the gravimetric method and the electrochemical method correlate well with each other. However, the depth of corrosion based on the gravimetric method was on an average six times greater than that based on corrosion rate measurements. The reason for this is not fully known to the author. It seems that of all the measurement results, those that indicate the maximum values of corrosion rate are nearest to the correct level and some of the measurement results show too low a rate of Corrosion, Thus a single measurement may not be adequate to obtain a reliable value of corrosion rate.
机译:该研究的目的是通过线性极化研究腐蚀速率测量的可靠性。还研究了其他电化学测量,例如腐蚀电位和混凝土电阻率。使用的测量装置是Gecor6 / 1 /。在实验室中制备了六种钢筋混凝土测试板。通过向混凝土混合物中加入氯化物来引发增强件的腐蚀。板坯储存在条件的气候室。通过在420天内通过平板的定期测量监测腐蚀速率,腐蚀电位和混凝土电阻率。研究了测量结果的散点。为了确定测量时段后,一些混凝土板的实际腐蚀速率。钢筋曝光,腐蚀量在视觉上并通过重量法评价。将观察到的腐蚀量与基于腐蚀速率测量计算的理论量的腐蚀进行了比较。由重量法和电化学方法确定的腐蚀深度彼此相吻合得很好。然而,基于重量法的腐蚀深度平均比基于腐蚀速率测量的六倍。作者对此的原因并不完全了解。似乎所有测量结果都是指示腐蚀速率的最大值最接近正确水平的那些,其中一些测量结果显示出太低的腐蚀速率,因此单个测量可能不足以获得可靠的腐蚀率的价值。

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