Electrophoretic Deposition of Nitrogen-Boron Co-Doped Graphene as High Performance Electrode for Next Generation Supercapacitors

摘要

In this study, we report the electrophoretic deposition (EPD) of nitrogen-boron co-doped graphene (NBG) synthesized via simple hydrothermal method and subsequent annealing at 750°C in reducing environment. The structural, chemical-compositional and morphological investigations of the as synthesized NBG have been investigated using X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The electrochemical properties of the samples have been studied via cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) cycling and electrochemical impedance spectroscopy (EIS) in a conventional three-electrode system using 6M KOH aqueous electrolyte. The EPD grown binder free NBG electrode exhibits high specific capacitance of 217 Fg~(-1) at the scan rate of 5 mVs~(-1) which is about 1.2 times higher than the specific capacitance (180 Fg~(-1) at 5 mVs~(-1)) of pristine reduced graphene oxide synthesized via similar approach. Furthermore, this sample exhibits excellent rate capability, and ～103% retention after 8800 successive charge-discharge cycles at 1 Ag~(-1).