Electron-Transfer Stopped-Flow Method for the Spectroscopic Detection and Kinetic Analysis of Cation Radicals

摘要

In the electrochemical oxidation of aromatic molecules in aprotic solvents,the cation radicals are formed as a result of one-electron transfer.If such cation radicals are short-lived,the Spectroscopic detection with conventional methods should be very difficult due to the consecutive chemical and/or electrochemical reactions.