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NMR Relaxation Studies and Molecular Modeling of l-butyl-3-methyl Imidazolium PF6 BMIMPF6 and Related Ionic Liquids

机译:L-丁基-3-甲基咪唑鎓PF6 BMIM PF6及相关离子液体的NMR弛豫研究和分子建模

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The molecular reorientational dynamics of [BMIM][PF6] has been studied by ~(13)C NMR spectroscopy.The ~(13)C relaxation times and nuclear overhauser enhancement (NOE) measurements are used to determine reorientational correlation times.The continuous distribution of correlation times defined by Cole and Davidson that has been used to interpret the relaxation data of viscous liquids and glassy solids is used to model the [BMIM][PF6] and related systems.
机译:[Bmim] [PF6]的分子重组动态已经研究过〜(13)C NMR光谱。〜(13)C松弛时间和核传闻增强(NOE)测量用于确定重新定位相关时间。连续分布由COLE和Davidson定义的相关时间用于解释粘性液体和玻璃状固体的弛豫数据,用于模拟[BMIM] [PF6]和相关系统。

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