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Selection of the Cation Exchange Resin against Oxidized Degradation in BWR Condensate Demineralizer

机译:选择阳离子交换树脂在BWR凝结脱矿物中的氧化降解

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The condensate demineralizer (CD) is installed to keep the reactor water quality in high purity. The CD should keep enough ion removal efficiency at all times to take proper countermeasures against the main condenser cooling water leakage. The reactor water sulfate ion should be kept as low as possible to mitigate the possibility of IGSCC. The IGSCC is induced and accelerated by sulfate ion. One of the major sources of sulfate ion is leachables from strong acid type cation exchange resin (CER). On the other hand, it has appeared that anion exchange resin (AER) kinetics is interfaced by total organic carbon (TOC) leached from the CER. It is very important to use high stability CERs against oxidized degradation to keep not only the reactor water sulfate ion in low level but also enough kinetics of the AER. This paper describes phenomena of the AER kinetics degradation and reactor water sulfate ion increase occurred at the same time and the CER stability measurements against oxidized degradation.
机译:安装冷凝物脱蛋白(CD)以保持高纯度的反应器水质。 CD应始终保持足够的离子去除效率,采取适当的对策对抗主冷凝器冷却水泄漏。反应器水硫酸盐离子应尽可能低,以减轻IGSCC的可能性。通过硫酸根离子诱导和加速IGSCC。硫酸根的主要来源是来自强酸型阳离子交换树脂(CER)的可浸出物。另一方面,似乎阴离子交换树脂(AER)动力学通过从CER浸出的总有机碳(TOC)接口。使用高稳定性的CERS抗氧化降解非常重要,以保持低水平的反应器水硫酸根,但也具有足够的动力学。本文描述了AER动力学降解的现象,并同时发生反应器水硫酸盐离子升高,并且CER稳定性测量对氧化降解进行稳定性测量。

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