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Selection of the Cation Exchange Resin against Oxidized Degradation in BWR Condensate Demineralizer

机译:BWR冷凝水脱盐器中抗氧化降解阳离子交换树脂的选择

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The condensate demineralizer (CD) is installed to keep the reactor water quality in high purity. The CD should keep enough ion removal efficiency at all times to take proper countermeasures against the main condenser cooling water leakage. The reactor water sulfate ion should be kept as low as possible to mitigate the possibility of IGSCC. The IGSCC is induced and accelerated by sulfate ion. One of the major sources of sulfate ion is leachables from strong acid type cation exchange resin (CER). On the other hand, it has appeared that anion exchange resin (AER) kinetics is interfaced by total organic carbon (TOC) leached from the CER. It is very important to use high stability CERs against oxidized degradation to keep not only the reactor water sulfate ion in low level but also enough kinetics of the AER. This paper describes phenomena of the AER kinetics degradation and reactor water sulfate ion increase occurred at the same time and the CER stability measurements against oxidized degradation.
机译:安装了冷凝水脱盐器(CD),以确保反应器水质处于高纯度。 CD应始终保持足够的离子去除效率,以采取适当的对策,以防止主冷凝器冷却水泄漏。反应器中的水硫酸根离子应保持尽可能低,以减轻IGSCC的可能性。 IGSCC由硫酸根离子诱导和加速。硫酸根离子的主要来源之一是来自强酸型阳离子交换树脂(CER)的可浸出物。另一方面,似乎阴离子交换树脂(AER)动力学与从CER浸出的总有机碳(TOC)接触。使用高稳定性的CER防止氧化降解非常重要,不仅要使反应器中的水硫酸根离子保持在较低的水平,还要使AER保持足够的动力学。本文描述了同时发生AER动力学降解和反应器水硫酸盐离子增加的现象,以及针对氧化降解的CER稳定性测量。

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