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EFFECT OF TEMPERATURE AND TEMPERATURE UNIFORMITY ON PLASMA AND DEVICE STABILITY

机译:温度和温度均匀性对等离子体和装置稳定性的影响

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We have investigated the changes in the cathode potential in a dc discharge of silane and hydrogen used to deposit the intrinsic layer of p-i-n type solar cells at deposition rates from 1 to 10A/s with the superstrate temperature at 200°C and 250°C. Under plasma conditions that lead to higher deposition rates (5-10A/s), fluctuations of the cathode potential which are suggestive of the formation and de-trapping of particulates in/from the plasma, are observed at 200°C but disappear at 250°C. Improvement of the temperature uniformity over the plasma region from 1.7°C/cm to 0.7°C/cm removes the fluctuations of the cathode potential even at 200°C, indicating that the particulates are formed predominantly at the plasma boundary. Consequently, the stability of solar cells with i-layers deposited at ~10A/s in the center of the plasma region at the same superstrate temperature improved by 26% suggesting that multiple silicon containing molecules diffuse from the edge to the center of the plasma region.
机译:我们研究了在硅烷的直流放电中的阴极电位的变化,用于将P-I-N型太阳能电池的固有层沉积在沉积速率下,以在200℃和250℃下以沉积的温度沉积1至10A / s。在等离子体条件下其导致更高的沉积速率(5-10A /秒),阴极电势的波动,这是暗示的形成和颗粒的中/从等离子体脱俘获的,都在200℃下观察到,但在250消失°C。从1.7℃/ cm至0.7℃/ cm的等离子体区域的温度均匀性的改善消除了即使在200℃下也会去除阴极电位的波动,表明颗粒在等离子体边界处主要形成。因此,在相同的叠加温度下沉积在〜10a / s的沉积在〜10a / s的〜10a / s中的太阳能电池的稳定性提高了26%,表明多个含硅分子从边缘漫射到等离子体区域的中心。

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