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Thermally sprayed multilayer coatings as electrodes and dielectrics in high efficiency ozonizer tubes

机译:热喷涂的多层涂层作为电极和高效臭氧器管中的电极和电介质

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Ozone is an environmental benign chemical substance, being able to replace commonly used chlorine compounds in many processes. It is one of the strongest oxidants surpassed only by flourine in its oxidising power. Therefore ozone is used as a germicide and viricide for the treatment of potable and waste water, as well as for bleaching processes and in further chemical oxidation steps. In general large quantities of ozone are generated by dielectric barrier discharges (DBD) [1, 2, 3, 4]. Only these non-equilibrium gas discharges are suited for an effective ozone generation and since ozone is not chemically stable, and therefore would decay during transportation, it is produced in discharge tubes on site where it is needed in tailored capacity. But since the drawback of fairly high production costs of ozone -especially for large quantities - has not overcome yet, large amounts of hazardous chlorine compounds are still used. The aim of this research project is the development of a novel powerful ozonizer tube which cuts down the production costs and thus causes ozone to be an economically competitive alternative in comparison to traditionally used chlorine compounds [5, 6, 7, 8], Standard ozonizer tubes consist of a borosilicate glass tube with a thermal sprayed metallic coating applied to the inner surface of the tube, that serves as the HV-electrode. In this arrangement the tube itself serves as a dielectric. The metallic inner tube surface is electrically connected via metal brushes. The borosilicate glass is restricted to a permittivity of ε_r ≈ 4,6.
机译:臭氧是一种环保良性化学物质,能够在许多过程中替代常用的氯化合物。它是仅在氧化能力中仅泛氟的最强氧化剂之一。因此,臭氧用作治疗饮用和废水的杀菌剂和原发生物,以及漂白过程和进一步的化学氧化步骤。通常,大量的臭氧由介电阻挡放电(DBD)[1,2,3,4]产生。只有这些非平衡的气体排放适用于有效的臭氧生成,由于臭氧不具有化学稳定,因此在运输过程中衰减,它在出位的出位管中产生,其中需要定制容量。但由于臭氧的缺点的缺点 - 专为大量的臭氧 - 尚未克服,仍未克服,仍然使用大量的危险氯化合物。该研究项目的目的是开发一种新型强大的臭氧器管,从而降低了生产成本,从而导致臭氧是一种经济竞争的替代方案,与传统使用的氯化合物[5,6,7,8],标准臭氧器相比管由硼硅酸盐玻璃管组成,具有施加到管内表面的热喷涂金属涂层,其用作HV-电极。在这种布置中,管本身用作电介质。金属内管表面通过金属刷电连接。硼硅酸盐玻璃仅限于ε_R≈4,6的介电常数。

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