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Constitutive Model for Thermomechanical Behavior of Curing Thermosetting Polymers

机译:固化热固性聚合物热机械性能的本构模型

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The mechanical and rheological behavior of thermosetting polymers during cure is not fully understood. Today's models and simulations make use of ad hoc approximations that relate the strength properties of thermosets linearly to the degree of cure. These assumptions work well when predicting the thermomechanical behavior of thin parts, but are not valid for thick parts where the phase change is space dependent and significantly contributes to the residual stress build-up. Within this work, different thermoanalytical measurements were carried out on a standard SMC paste without any fiber reinforcement. Thin plates, were compression molded at different mold temperatures for different periods of time. The degree of cure of the specimens were determined using DSC and TGA measurements. The modulus as a function of temperature was measured using a three point bending DMA setup. Using time-temperature superposition and cure dependent shifts, a master curve that represents a reduced modulus as a function of a reduced temperature was generated. To perform thermomechanical analysis of curing thermosetting parts, a model that fits the reduced stiffness master curve was developed
机译:固化过程中热固性聚合物的机械和流变行为尚未完全理解。今天的模型和仿真利用临时近似,该近似值与固化程度线性的热固性的强度特性相关。当预测薄零件的热机械行为时,这些假设很好地工作,但对于相变是依赖性的厚部件而言,对厚部件无效,并且显着促进残余应力积聚。在这项工作中,在标准的SMC浆料上进行了不同的热分析测量,没有任何纤维增强。薄板,在不同的模具温度下压缩模塑不同的时间。使用DSC和TGA测量测定标本的固化程度。使用三点弯曲DMA设置测量作为温度函数的模量。使用时间温度叠加和固化依赖性换档,产生作为作为降低温度的函数的模量减少的主曲线。为了执行固化热固性零件的热机械分析,开发了一种拟合刚度较低主曲线的模型

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