Widely available silver and arsenic bearing concentrates can be smelted to produce a discardable slag, a base metal speiss, and a crude silver button which is easily separated from the other phases after solidification. This paper discusses the development of a novel process as an alternative to existing nitric acid leach methods for the production of high purity silver from the raw silver button. Direct electro-refining of the raw silver anode in a sulphate medium is integrated with downstream purification and recycling modules that are customized to allow efficient recovery of silver and saleable by-products. The test results, flowsheet alternatives and process details are presented and discussed in terms of overall technical feasibility economical viability and environmental compliance considerations.
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