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SINTER-BONDING BEHAVIOR OF Cr_3C_2 BASE CERMETS ON STEELS

机译:CR_3C_2基础CERMETS对钢上的烧结行为

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Bonding of Cr_3C_2 base cermets onto steel substrates by powder metallurgical technique, so called sinter-bonding, is expected to be a smart process to produce a composite material possessing high strength. This process requires that a densification of the cermet and a bonding at the interface between the cermet and the substrate proceed simultaneously. Pseudo-ternary Cr_3C_2-Ni-WB cermets can be sintered to full density at temperatures lower than 1450K. The liquid phase formed by the eutectic reaction between added WB and Ni considerably reduces the sintering temperature of the Cr_3C_2-Ni cermet, providing the feasibility of the sinter-bonding with AISI 1045. In the case of the cermet without WB, a satisfactory sinter-bonded body could not be obtained, because an excessive reaction betwen Cr_3C_2 particles and AISI 1045 prior to the densification of the cermet generates a large amount of a liquid phase at the interface and caused remarkable grain coarsening of the carbides and reduction of bonding strength. The coarsened carbide particles near the interface formed by a direct reaction between Cr_3C_2 particles and AISI 1045 were identified as a M_7C_3 type chromium carbide containing W and Fe. WB addition to the Cr_3C_2-Ni cermet is essential to obtain the satisfactory bonding strength and microstructure between the cermet and the steel substrate.
机译:通过粉末冶金技术,所谓的烧结粘合,Cr_3C_2碱金属陶瓷的粘结到钢基材预计是一个智能过程,以产生具有高强度的复合材料。该过程要求CERMET的致密化和在金属陶瓷和基板之间的界面处的粘合同时进行。伪三元CR_3C_2-NI-WB金属陶瓷可在低于1450K的温度下烧结至全密度。通过添加的WB和Ni之间的共晶反应形成的液相显着降低了Cr_3C_2-Ni金属陶瓷的烧结温度,提供了与AISI 1045的烧结粘合的可行性。在没有WB的情况下,令人满意的烧结 - 不能获得粘合体,因为CR_3C_2颗粒和AISI 1045之间的过度反应在金属陶瓷之前在界面产生大量的液相,并且导致碳化物的显着晶粒粗化和粘合强度的降低。通过Cr_3C_2颗粒和AISI 1045之间的直接反应形成的界面附近的碳化物颗粒均被鉴定为含有W和Fe的M_7C_3型碳化铬。添加到CR_3C_2-NI CERMET的WB是必不可少的,以获得金属陶瓷和钢基材之间的令人满意的粘合强度和微观结构。

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