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EFFECT OF NITROGEN ON HYDROGEN EMBRITTLEMENT OF AUSTENITIC STAINLESS STEELS BASED ON TYPE 316LN

机译:基于316Ln型奥氏体不锈钢氢脆的氮气脆化作用

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The effect of nitrogen on hydrogen gas embrittlement (HGE) in 1 and 70 MPa hydrogen and internal reversible hydrogen embrittlement (IRHE) of austenitic stainless steels of 17Cr11Ni2Mo(0.4 in max.)N alloys, based on type 316LN, was investigated by slow strain rate technique tests at room temperature in comparison with the effect of Ni on HGE and IRHE of Ni-added type 316 stainless-steel-alloys. For the nitrogen-added alloys, HGE and IRHE decreased with increasing nitrogen content, where α' martensitic transformation occurred. HGE was not observed but IRHE was observed above the nitrogen content, where austenite is completely stabilized by nitrogen. Hydrogen-induced fracture related to the strain-induced α' martensite structure was observed in HGE specimens and that together with brittle transgranular fracture was observed in IRHE specimens. HGE of the nitrogen-added alloys is larger than that of the Ni-added alloys in the Ni_(eq) range, where α' martensitic transformation occurred. No HGE was observed in both the nitrogen-added alloys and the Ni-added alloys, but IRHE was observed in not the Ni-added alloys but the nitrogen-added alloys above the Ni_(eq), where no martensite is identified in both alloys. It is discussed that the α'martensite and the austenite of the nitrogen-added alloys were more sensitive to HGE or IRHE than those of the Ni-added alloys.
机译:基于316LN的17Cr11Ni2MO(0.4英寸)N合金的奥氏体不锈钢和内部可逆氢气脆化(IRHE)的氮气脆化(HGE)对1和70MPa氢气和内部可逆氢气脆化(IRHE)的影响速率技术在室温下试验,与Ni对Ni加入316型不锈钢合金的影响和IRHE的影响相比。对于氮气的合金,Hge和IrHe随着氮含量的增加而降低,其中α'马氏体转化发生。未观察到Hge,但在氮含量之上观察到IRHE,其中奥氏体通过氮气完全稳定。在HGE样本中观察到与应变诱导的α'马氏体结构相关的氢诱导的骨折,在IRHE标本中观察到与脆性转响骨折一起。氮气添加的合金大于Ni_(EQ)范围内的Ni加入合金的HGE,其中发生α'马氏体转化。在氮气添加的合金和Ni加入的合金中没有观察到Hge,但在Ni_(EQ)上方的Ni加入的合金中观察到IRHE,而不是在两种合金中鉴定马氏体的氮添加合金。讨论了α'martensite和氮添加合金的奥氏体对Hge或IRHE更敏感而不是Ni加入的合金。

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