首页> 外文会议>ASME Pressure Vessels and Piping Division/K-PVP conference;PVP2010 >EFFECT OF NITROGEN ON HYDROGEN EMBRITTLEMENT OF AUSTENITIC STAINLESS STEELS BASED ON TYPE 316LN
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EFFECT OF NITROGEN ON HYDROGEN EMBRITTLEMENT OF AUSTENITIC STAINLESS STEELS BASED ON TYPE 316LN

机译:氮对基于316LN型奥氏体不锈钢的氢脆化的影响

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The effect of nitrogen on hydrogen gas embrittlement (HGE) in 1 and 70 MPa hydrogen and internal reversible hydrogen embrittlement (IRHE) of austenitic stainless steels of 17Cr11Ni2Mo(0.4 in max.)N alloys, based on type 316LN, was investigated by slow strain rate technique tests at room temperature in comparison with the effect of Ni on HGE and IRHE of Ni-added type 316 stainless-steel-alloys. For the nitrogen-added alloys, HGE and IRHE decreased with increasing nitrogen content, where α' martensitic transformation occurred. HGE was not observed but IRHE was observed above the nitrogen content, where austenite is completely stabilized by nitrogen. Hydrogen-induced fracture related to the strain-induced α' martensite structure was observed in HGE specimens and that together with brittle transgranular fracture was observed in IRHE specimens. HGE of the nitrogen-added alloys is larger than that of the Ni-added alloys in the Ni_(eq) range, where α' martensitic transformation occurred. No HGE was observed in both the nitrogen-added alloys and the Ni-added alloys, but IRHE was observed in not the Ni-added alloys but the nitrogen-added alloys above the Ni_(eq), where no martensite is identified in both alloys. It is discussed that the α' martensite and the austenite of the nitrogen-added alloys were more sensitive to HGE or IRHE than those of the Ni-added alloys.
机译:通过慢应变研究了氮对17Cr11Ni2Mo(最大0.4)最大奥氏体不锈钢在1和70 MPa氢气中的氢气脆化(HGE)和内部可逆氢气脆化(IRHE)的影响在室温下进行了高速率技术测试,并比较了镍对添加镍的316型不锈钢合金的HGE和IRHE的影响。对于含氮合金,随着氮含量的增加,HGE和IRHE降低,发生α'马氏体相变。未观察到HGE,但在氮含量以上观察到IRHE,其中奥氏体被氮完全稳定。在HGE标本中观察到与应变诱发的α'马氏体结构有关的氢致断裂,在IRHE标本中观察到与脆性的经晶断裂一起。在发生α′马氏体相变的Ni_(eq)范围内,氮添加合金的HGE大于镍添加合金的HGE。在添加氮的合金和添加镍的合金中均未观察到HGE,但是在添加Ni_(eq)以上的添加氮的合金中未观察到IRHE,但在两种合金中均未发现马氏体,但未在添加Ni的合金中观察到IRHE。 。讨论的是,与添加镍的合金相比,添加氮的合金的α'马氏体和奥氏体对HGE或IRHE更为敏感。

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