Effect of Waste-Derived Calcium Sulfate Additions on the Tribological Properties of Sintered Steel-Based Material

摘要

This study examined the effect of waste-derived calcium sulfate additions (2 to 8 weight percent) on the tribological properties of a sintered high-carbon steel material, commonly used for frictional applications. The calcium sulfate powder was obtained by crushing and subsequent calcination of waste plaster molds previously used for slip casting of ceramics. Samples were made using the powder metallurgy method. Powder mixtures were uniaxially die compacted and sintered at 1,100 °C for 30 minutes in a reducing atmosphere. It was found that the density of the samples decreased with increased amounts of calcium sulfate. This was due to the lower theoretical density of the calcium sulfate as well as volumetric expansion of the samples. Ball-on-disc tribological testing was performed at room temperature. The addition of calcium sulfate resulted in an increase of the kinetic friction coefficient. The measured wear volume was slightly reduced with the addition of calcium sulfate less than 6 weight percent, beyond which the wear increased. The hardness of the samples was reduced with the addition of calcium sulfate. Increased calcium sulfate content decreased the sample deformation resistance while increasing the kinetic friction coefficient and the wear. This was likely due to the microstructural changes of the samples, which will be discussed.