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Synthesis and properties of amphiphilic hyperbranched polyethers as pigment dispersant

机译:两亲子石超支化聚醚作为颜料分散剂的合成与性质

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Hyperbranched polymers possess prominent properties such as low viscosity, good solubility, high rheological property, environmental non-toxic,and so on, which have potential applications in coatings. In this study, the amphiphilic hyperbranched polyethers (AHPs) consisting of hydrophobic hyperbranched polyethers core and hydrophilic poly (ethylene glycol) arms with different degree of branching (DB) under various reaction temperatures was prepared by the cation ring-opening polymerization. Their structures were characterized by IR, ~(13)CNMR and GPC. Their dispersion properties for pigment particles were investigated. The AHP47 with 0.47 DB was found to have good dispersion properties for Yellow HGR. This work would provide experimental data and theoretical foundation for the application of hyperbranched polyethers in environmental protection coating.
机译:超支化聚合物具有突出的性质,如低粘度,良好的溶解度,高流变性,环境无毒等,涂层含有潜在的应用。在本研究中,通过阳离子开环聚合制备了由疏水性超支化聚醚组成的两亲的超支化聚醚(AHPS)组成,具有不同程度的分支(DB)的亲水性聚醚臂(DB)。其结构的特征在于IR,〜(13)CNMR和GPC。研究了颜料颗粒的分散性质。发现具有0.47dB的AHP47具有良好的黄HGR分散性。这项工作将为在环保涂层中应用超支化聚醚的应用实验数据和理论基础。

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