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THE EFFECTS OF TEMPERATURE ON THE WATER WEAKENING OF CHALK BY SEAWATER

机译:温度对海水粉笔水弱化的影响

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Seawater is injected into the high temperature North Sea chalk reservoirs to improve oil recovery with great success.Increased compaction of the rock,which also is a significant contribution to the oil displacement,is observed in the water-flooded area.Very recent laboratory studies at high temperature documented that enhanced compaction took place when chalk cores under stress were flooded by seawater.The special composition of seawater regarding reactive ions towards the chalk surface appeared to be the reason.In this paper,two different water-weakening mechanisms are discussed: 1) Substitution of Ca~(2+) from the chalk surface by Mg~(2+) present in seawater(dolomitization) at inter granular contacts and 2) Chemical dissolution.The effect of temperature is opposite for the two mechanisms,and in the present paper,the impact of temperature on chalk compaction is studied both in a static and dynamic way using triaxial cells under hydrostatic conditions. Distilled water was used as a reference fluid in the static tests at 80-130 °C.The mechanical strength of chalk containing seawater was opposite to chalk containing distilled water.With seawater,the chalk became weaker as the temperature increased, while using distilled water the chalk became stronger as the temperature increased.In the dynamic creep tests,at 70-90 °C,the cores flooded with seawater were significantly weaker than cores flooded with seawater without sulfate,and the difference in mechanical strength decreased as the temperature decreased.The mechanism for enhanced chemical induced weakening of chalk is discussed.
机译:海水注入高温北海粉笔储层,以提高石油回收,取得了巨大的成功。在水利地区观察到岩石的压实,这也是对石油排量的重大贡献。最近的实验室研究当压力下的粉笔核心被海水中淹没时,较高的温度造成了增强的压实。关于粉笔表面反应离子的海水的特殊组成似乎是本文讨论了两种不同的水弱机制:1 )在粒状触点中的海水(二元化)中的Mg〜(2+)从粉笔表面取代Ca〜(2+),2)化学溶解。温度对两种机制相反,以及本文在静水压条件下使用三轴电池以静态和动态的方式研究了温度对粉笔压实的影响。蒸馏水在80-130℃下用作静态试验中的参考流体。含有海水的粉笔的机械强度与含蒸馏水的粉笔相反。随着温度的增加,粉笔变弱,同时使用蒸馏水。随着温度的增加,粉笔变得越来越强。在动态蠕变试验中,在70-90°C时,与海水充斥着的核心显着弱于不含硫酸硫酸盐的核心,随着温度降低而减少机械强度的差异。讨论了增强化学诱导的粉笔弱化的机制。

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