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Crystallization Kinetics and Thermal Resistance of Bamboo Fiber Reinforced Biodegradable Polymer Composites

机译:竹纤维增强可生物降解聚合物复合材料的结晶动力学和热阻

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Bamboo fiber reinforced biodegradable polymer composites were prepared in this study. Biodegradable poly(butylene succinate) (PBS) was blended with bamboo fiber in a twin screw extruder with varied bamboo content from 20-0wt%. PBS/bamboo fiber composites were fabricated by compression molding process. The effect of bamboo fiber contents on properties of the composites was investigated. Non-isothermal crystallization kinetic study of the composites was investigated based on Avrami equation. The kinetic parameters indicated that bamboo fiber acted as heterogeneous nucleation and enhanced crystallinity of the composites. Bamboo fiber was well dispersed on PBS matrix and good adhered with the matrix. Tensile strength of the composites slightly deceased with adding bamboo fiber. However, tensile modulus and impact strength of the composites increased when increasing bamboo fiber contents. It can be noted that bamboo fiber promoted crystallization and crystallinity of PBS in the composites. Therefore, the composites were better in impact load transferring than neat PBS, which exhibited improving on impact performance of the composites.
机译:在本研究中制备竹纤维增强的可生物降解的聚合物复合材料。将可生物降解的聚(丁烯琥珀酸盐)(PBS)与双螺杆挤出机中的竹纤维混合,其中竹含量为20-0wt%。通过压缩成型方法制造PBS /竹纤维复合材料。研究了竹纤维内容对复合材料性能的影响。基于AVRAMI方程研究了复合材料的非等温结晶动力学研究。动力学参数表明,竹纤维作用为复合材料的异均匀成核和增强的结晶度。竹纤维很好地分散在PBS基质上,并用基质粘附。复合材料的拉伸强度略微死亡,加入竹纤维。然而,在增加竹纤维内容物时复合材料的拉伸模量和冲击强度增加。可以注意到,竹纤维在复合材料中促进了PBS的结晶和结晶度。因此,复合材料的影响载荷转移比纯PBS更好,这表现出改善复合材料的冲击性能。

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