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Thermal Conversion of Cs-exchanged IONSIV IE-911 into a Novel Caesium Ceramic Wasteform by Hot Isostatic Pressing

机译:CS-Exchanged ICESIV IE-911的热转化通过热等静压进入新型陶瓷废物

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Hot Isostatic Pressing of Cs-exchanged IONSIV IE-911 samples is shown to produce a mixture of ceramic phases, the nature and mass fractions of these have been determined by Rietveld analysis of powder X-ray diffraction data. The main Cs phase that forms is Cs_2TiNb_6O_(18), after this reaches approximately 30% of the total crystalline content the remaining Cs is partitioned into Cs_2ZrSi_6O_(15). Durability tests using the PCT-B method for 7 days at 90 °C with deionised water lead to Cs leach rates of 0.032 and 0.038 g·m~(-2)·day~(-1) for samples exchanged to 6 and 12 wt% Cs, respectively, indicating a durable wasteform is produced.
机译:示出了CS-Exchanged的CS-Exchance的热等静压IE-911样品被示出为产生陶瓷相的混合物,这些粉末X射线衍射数据的RIETVELD分析已经确定了这些陶瓷阶段的混合物,这些性质和质量分数已经确定。形成的主要CS阶段是CS_2TINB_6O_(18),在此达到总结晶含量的大约30%之后,将剩余的CS划分为CS_2ZRSI_6O_(15)。使用PCT-B方法在90℃下使用PCT-B方法的耐久性试验与去离子水导致CS乳液速率为0.032和0.038g·m〜(2)·日〜(-1),用于更换为6和12重量的样品分别产生耐用废物的%CS。

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