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HYDROXYPROPYL CELLULOSE AS PREPARATION OF PROCESSABLE HIGHLY CONDUCTIVE POLYANILINE

机译:羟丙基纤维素作为可加工高导电聚苯胺的制备

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Preparation of highly conducting and processable polyaniline was carried out in the presence of anionic surfactant AOT (di-2-ethyl hexylsulfosuccinic acid sodium salt) together with hydroxypropylcellulose(HPC) as processable highly conductive polyaniline. The good environmental and electrical stability of PANI seems to be very promising conducting polymer. Several types of acid and dopants can be used to synthesize highly conductive PANI with conductivity as high as 300S/cm. These were achieved by so-called 2-steps method: first PANI in emeraldine salt (ES) form was synthesized and then dedoped into emeraldine base (EB) form; secondly the EB powder was redoped with dopant (CSA, DBSA and etc) and dissolved in m-cresol and cast into film.[1-3] This method is cost and time consuming as compared to our method, where the PANI is prepared in the presence of dopant(AOT) and then "in-situ" secondary doped by direct addition of m-cresol in the PANI solution.[4]
机译:在阴离子表面活性剂AOT(二-2-乙基己酰磺酸钠酸钠)的存在下,在与羟丙基纤维素(HPC)一起作为可加工的高导电聚苯胺,在阴离子表面活性剂AOT(二-2-乙基己基硫磺酸钠)的存在下进行高导电和加工聚苯胺。 Pani的良好环境和电气稳定性似乎是非常有前途的导电聚合物。可以使用几种类型的酸和掺杂剂合成具有高达300℃/ cm的电导率的高导电胰腺。这些通过所谓的2步骤方法来实现:合成祖母绿盐中的第一个PANI,然后将其用于祖美碱(EB)形式;其次,用掺杂剂(CSA,DBSA等)重新转化EB粉末并将其溶解在M-甲酚中并浇铸成薄膜。[1-3]与我们的方法相比,该方法是成本和耗时的,而是持续的方法,在其中制备PANI通过在PANI溶液中直接加入M-CRESOL,掺杂剂(AOT)和“原位”次级的存在。[4]

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