Multifold Nucleation Rate Surfaces over Phase Diagrams with Monotropic Phase Transitions

摘要

The theory of supersaturated vapor nucleation for systems with monotropic polymorphic phase transitions does not entirely correspond to the modern requirements for scientific and practical applications. Semiempirical design of the nucleation rate surfaces looks like a promising way to get more reliable data for that case. Examples of the topology of nucleation rate surfaces for systems with monotropic polymorphic transitions constructed using a new concept for the semiempirical design of such surfaces over p-T phase equilibrium diagrams, where p is pressure and T is temperature, are presented.