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Role of mean force field in dynamics of glass forming binary mixture with and without attractive interactions

机译:平均力场在形成二元混合物的动态中的作用,无吸引互动

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The Week-Chandler-Anderson (WCA) model for Lennard-Jones liquid shows that at high densities the structure of the liquid depends mostly on repulsive interactions, and attractive interaction has a small perturbation effect. Recent studies on the WCA model of the glass-forming binary mixture at high density supercooled state shows that even at high densities and at low temperatures the dynamics of the binary mixture and its WCA model have difference in the relaxation dynamics of the system, and only at very high densities their dynamics approaches each other. In this study, we show that when the mean force experienced by a particle are the same the relaxation dynamics of the system are the same. The mean force is a measure of the degree of caging of a particle as supercooling increases. Thus, we provide a microscopic origin of the observed difference in the relaxation dynamics.
机译:Lennard-Jones Light的周 - Chandler-Anderson(WCA)模型表明,在高密度下,液体的结构主要取决于排斥相互作用,并且有吸引力的相互作用具有小的扰动效果。 最近在高密度过冷状态下形成玻璃形成二元混合物的WCA模型的研究表明,即使在高密度和低温下,二元混合物的动态和其WCA模型的动态也有差异,并且仅限于系统的松弛动力学。 在非常高的密度下,他们的动态互相接近。 在这项研究中,我们表明,当粒子所经历的平均力相同时,系统的松弛动力学是相同的。 平均力是作为过冷却的粒子的捕获程度的量度。 因此,我们提供了弛豫动态的观察到差异的微观起源。

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