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Multiphysics Model of the Anode of a Direct Methanol Fuel Cell

机译:直接甲醇燃料电池阳极的多体型模型

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A multiphysics across-the-channel model is presented for the anode of a liquid-feed Direct Methanol Fuel Cell (DMFC). The model considers both two-dimensional (2D) single-phase anisotropic transport of methanol in the anode gas diffusion layer (GDL) and anisotropic electron transport from the catalyst layer to the current collector rib, coupled to a one- dimensional (1D) model for the membrane and the cathode, which describes the electrochemical reactions kinetics, water and methanol crossover, and oxygen transport from the cathode channel to the cathode catalyst layer. As new contribution, the 2D model takes into account the effects of the inhomogeneous compression of the GDL associated with the repetitive rib-channel pattern, including non-uniform porosity, diffusivity and bulk electrical conductivity distributions, as well as non-uniform contact resistances over the GDL-rib and -membrane interfaces, which affect mass and charge transport phenomena. As a straightforward application, we have investigated the effect of the clamping pressure acting on the stack on the overall fuel cell performance.
机译:介绍了液体饲料直接甲醇燃料电池(DMFC)的阳极的跨通道模型的多体学。该模型认为阳极气体扩散层(GDL)中甲醇的二维(2D)单相各向异性传输和从催化剂层到集电器肋的各向异性电子传输,耦合到一维(1D)模型对于膜和阴极,其描述了从阴极通道到阴极催化剂层的电化学反应动力学,水和甲醇交叉和氧气。作为新的贡献,2D模型考虑了与重复肋通道图案相关联的GDL的非均匀压缩的效果,包括非均匀孔隙率,扩散性和散装电导率分布,以及不均匀的接触电阻GDL-肋骨和 - 纤维界面,影响质量和电荷运输现象。作为一个直接的应用,我们研究了夹紧压力作用在整体燃料电池性能上的夹持压力的效果。

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