In this work we show the application of the angle-resolved spectroscopic reflectivity and polarimetry to the characterization of 2D photonic crystal structures in the form of slabs. The method we introduce is based on the combination of i) the numerical simulation of the interaction of the incident light with the photonic crystal, ii) the experimental measurement and iii) the comparison of both results. We show that the calculations predict the coupling of the incident light to photonic modes propagating inside the structure, related to the photonic bands of the infinite photonic crystal. We demonstrate this coupling in the experimental measurements for two kinds of samples consisting of 2D photonic crystal slabs of micro- and nanostructured photoresist on a silicon substrate.
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