Design, synthesis and crystal structure of chiral cavity structures via self complementary hydrogen bonding

摘要

Organic tubular assemblies constitute supramolecular structures with potential applications in chemistry and biology. Due to tunable properties their use has a potential in molecular receptor synthesis, ion channel construction, supramolecular polymer preparation, etc. Herein we report on synthesis of supramolecular structures designed on the basis of chiral bicyclo[3.3.1]nonane fused with heterocyclic moieties including 4-oxo-5-azaindole and other frameworks incorporating self-complementary hydrogen bonding sites.