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Relevant Thermodynamical Functions for High Supercooling Studies

机译:高过冷研究的相关热力学功能

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In the past decade the development of Fast Scanning Calorimetry (FSC) [1] has enabled the study of materials and substances at high supercoolings; amorphization; and crystallization from both high and low temperatures. These breakthroughs boost up the use of TA&C in studies of scientific interest and industrial applications. The rationale for the success of this development is, firstly, that most materials and substances are in metastable states, which scientifically interesting states can now be studied in much more detail than before. Secondly, in practice, industrial processes that occur at much higher rates than realizable using Standard DSC can now be supported much better because the FSC can mimic actual scan rates. Thermal history - specifically cooling and heating rates - and sample / product treatment can, by switching between metastable phases, change materials behavior drastically, influencing end properties. Therefore, it is of high importance to study and understand phenomena related to metastability like supercooling, hot crystallization, cold crystallization, recrystallization (after melting) and remelting, annealing etc.
机译:在过去的十年中,快速扫描量热法(FSC)[1]的开发使高超消耗的材料和物质的研究能够研究;黑色化;并从高温和低温中结晶。这些突破促进了TA&C在科学兴趣和工业应用研究中的使用。这一发展成功的理由首先,大多数材料和物质都处于亚稳态,现在可以比以前更详细地研究科学上有趣的状态。其次,在实践中,现在可以更好地支持与使用标准DSC的可实现更高的速率发生的工业过程,因为FSC可以模仿实际扫描速率。热历史 - 通过在亚稳阶段之间切换,稳定地改变材料行为,影响最终性能,特别是冷却和加热速率 - 以及样品/产品处理可以改变材料行为。因此,它是非常重要的研究和了解有关亚稳态过冷一样,热结晶,冷结晶,重结晶(熔点之后)现象和重熔,退火等

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