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ANALYTICAL SOLUTION FOR TWO-PHASE FLOW IN PEMFC GAS DIFFUSION LAYER

机译:PEMFC气体扩散层中两相流的分析解

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Thermal and water management is critical to fuel cell performance. It has been shown that gas diffusion layer (GDL) can impose the mass transport limit; for example, it can block the reactant transport to active layer when flooding occurs at high current density conditions. Micro porous layer (MPL) in conjunction with backing layer (BL) has been used as a GDL material and was shown to be effective for water management. To study the transport processes in GDL and MPL modified GDL, an analytical solution is derived current study for calculation of two-phase, multicomponent transport in GDL. Two models were considered, the unsaturated flow model (UFM) and the separate flow model (SFM). Comparison of the calculated saturation level and oxygen mass fraction shows that UFM calculation can underestimate, as well as overestimate the saturation and oxygen concentration. The SFM was used to study the effects due to GDL property variations. The calculation shows that increase in liquid water transport in an MPL modified GDL is due to the abrupt change of liquid water flow rate when a step change in porosity or permeability is imposed. The calculation further shows that particle size of around 1 urn would be a good choice for MPL as it results in higher oxygen concentration at active layer and lower saturation in GDL.
机译:热量和水管理对燃料电池性能至关重要。已经表明,气体扩散层(GDL)可以施加质量分流限制;例如,当在高电流密度条件下发生洪水时,它可以阻断反应物传输到有源层。微多孔层(MPL)与背衬层(BL)一起用作GDL材料,并且显示用于水管理有效。为了研究GDL和MPL改性GDL的运输过程,推导了对GDL中的两相,多组分传输计算的当前研究的分析解决方案。考虑了两种模型,不饱和流模型(UFM)和单独的流量模型(SFM)。计算饱和水平和氧气质量分数的比较表明,UFM计算可以低估,以及高估饱和度和氧浓度。 SFM用于研究由于GDL性能变化引起的影响。该计算表明,MPL改性GDL中的液体水输送的增加是由于施加孔隙率或渗透率的步骤变化时液体水流速的突然变化。该计算进一步表明,大约1瓮的粒度为MPL是MPL的良好选择,因为它导致在活性层的较高氧浓度和GDL中较低的饱和度。

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