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MACROKINETICS OF METHANE CONVERSION AT SUPERADIABATIC FILTRATION COMBUSTION

机译:超级焊接过滤燃烧下甲烷转化的大转发剂

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Filtration combustion regimes, e.g., combustion of gases in porous media or counterflow gasification of a solid fuel, provide a basis for energy-saving technologies. Due to internal heat recuperation, they allow attaining superadiabatic heating, i.e., the resulting temperatures are high enough to perform perfect chemical conversion at a low net heat release. Substantial progress in the description of these technologies has been made recently (see [1] and references therein). The mathematical modeling of such systems is still a topical problem. It is apparently unrealistic to determine the optimal conditions for such processes using direct integration of a complete set of equations for heat and mass transfer as well as chemical kinetics. Due to multiple governing parameters, such, calculations are complicated and the problem of distinguishing the crucial governing parameters is very difficult to tackle. The kinetic description of gas-phase chain reactions of hydrocarbon oxidation is also a serious problem. It was shown analytically [2, 3] that the nonmonotonic behavior of such systems with wide variation of governing parameters reflects the complex geometry of the parametric domain of chain self-ignition in gaseous mixtures.
机译:过滤燃烧制度,例如,多孔介质中的气体燃烧或固体燃料的逆流气化,为节能技术提供基础。由于内部热回收,它们允许获得超级加热,即,所得温度足够高,以在低净热量释放下进行完美的化学转化。最近已经在这些技术的描述中进行了实质性进展(见[1]和其中参考)。这种系统的数学建模仍然是一个局部问题。通过直接整合用于热和传质的完整方程以及化学动力学,可以直接集成这些过程的最佳条件是不现实的。由于多个控制参数,这样的计算复杂,并且区分关键控制参数的问题非常难以解决。烃氧化的气相链反应的动力学描述也是一个严重的问题。其分析显示[2,3],这种系统具有宽的控制参数变化的这种体系的非单调行为反映了气态混合物中链式自燃的参数域的复杂几何形状。

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