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Uniform dispersion of fine oxides in steel slabs for the enhancement of HAZ toughness

机译:细氧化物在钢板中的均匀分散,提高HAZ韧性

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The charateristics of nonmetaliic inclusions such as composition, size, and number are informed to affect formation of the interagranular acicular ferrite(IAF) in an austenite grain greatly. Fine inclusions of Ti oxide, Ti nitride, Mn sulfide, and Ti oxide compexes have been reported to be especially effective for IAF nucleation[1-4]. There are mostly found to be Ti oxide complexes which are mainly composed of Ti-Mn-O-MnS-(TiN) in CC slab produced from BOF steel plant. The number, size, and composition are different from slab thickness. Its size is fine and its number is large in the slab surface but be coarse and of small number in the slab center. Ideally, nonmetaalic inclusions of number of 15,286ea/mm~3 whose size are 1~5 mu m is necessary in order to drive IAF nucleation in an austenite of 50 mu m diameter. It is very hard to meet the requirements of size and number through thickness of the CC slab of Ti oxide steel. In steel melt, oxides need not to be likely to agglomerate each other and need to keep stable solid phase. Therefore, to keep large number of fine inclusions in a CC slab, Mg deoxidizer was used to Ti oxide steel as Mg is reported to be strong deoxidizer and that its oxides have contact angle near 90 deg where they are not likely to agglomerate each other. Mg-Ti-(AI) oxide steel was produced from BOF-CC-Plate rolling process. In laboratory experiment nonmetaliic inclusions of steel ingots with various Mg and Al contents were identified by SEM and EDS, and phase changes with Mg ans Al addition was studied. Charateristics of nonmetaliic inclusions in the CC slabs such as size, number, and composition were invetigated through slab thickness with each heat by ESAA method which was developed by POSCO as one of the extraction methods by electroysis. It was compared with that of Ti oxide steel produced from BOF-CC-Plate rolling process. HAZ toughness at weld joint of the Mg-T i-(AI) oxide steel plates was also invetigated.
机译:非金属夹杂物的特征性,如组成,大小和数量,以大大大大造成奥氏体晶粒中的形状的针状铁氧体(IAF)的形成。据报道,Ti氧化物,Ti氮化物,Mn硫化物和Ti氧化物库的细含量对于IAF成核来特别有效[1-4]。大多数人发现是由来自BOF钢铁厂生产的CC板中的Ti-Mn-O-Mns-(TiN)组成的Ti氧化物复合物。数量,尺寸和组成不同于板坯厚度。它的尺寸很好,在板坯表面的数量很大,但在板坯中心的数量粗糙,数量少。理想情况下,必须为15,286ea / mm〜3的数量的非常规夹杂物,其尺寸为1〜5μm,是为了驱动50μm直径的奥氏体中的Iaf成核。很难满足通过Ti氧化物钢的CC板厚度的尺寸和数量的要求。在钢熔体中,氧化物不需要彼此附聚并且需要保持稳定的固相。因此,为了在CC板坯中保持大量细夹杂物,将Mg脱氧剂用于Ti氧化物钢,因为据报道Mg是强脱氧剂,并且其氧化物在90°附近接触角度,其中它们不太可能彼此附着。 Mg-Ti-(AI)氧化物钢由BOF-CC板轧制工艺制备。在实验室实验中,通过SEM和ED鉴定具有各种Mg和Al含量的钢锭的非金属夹杂物,并研究了用Mg ANS添加的相变。 CC板中的非金属夹杂物的特征性,如尺寸,数量和组合物,通过eSAA方法通过平板厚度来通过eSAA方法进行,该方法由Posco作为electroysis的提取方法之一开发。将其与由BOF-CC板轧制工艺产生的Ti氧化物钢进行比较。还终止了Mg-T I-(AI)氧化物钢板的焊接接头处的HAZ韧性。

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