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CONTINUOUS HYDROTHERMAL SYNTHESIS OF ZINC OXIDE NANOPARTICLES

机译:连续水热合成氧化锌纳米粒子

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Hydrothermal synthesis of zinc oxide (ZnO) nanoparticles and nanorods from zinc nitrate (Zn(NO_3)_2) and potassium hydroxide (KOH) solutions was carried out with a flow-through apparatus for continuous production and rapid heating of the starting solution to supercritical states. Effect of Zn(NO_3)_2 and KOH concentrations and flow rates on the particle size and morphology was examined at 673 K and 30 MPa. Nanoparticles having an average particle diameter of 22 nm was produced from 1.0×10~(-3) Zn(NO_3)_2 and 4.0×10~(-3) KOH aqueous solution at a total flow rate of 22.5g/min. Increasing the flow rate to 1.5 times larger value, nanorods having an average rod width of ca. 40 nm was produced.
机译:氧化锌(ZnO)纳米颗粒和纳米锌(Zn(NO_3)_2)和氢氧化钾(KOH)溶液的水热合成用流通装置进行,用于连续生产和快速加热起始溶液的超临界状态。在673k和30MPa中检查Zn(NO_3)_2和koh浓度和koh浓度对粒径和形态的影响。平均粒径为22nm的纳米颗粒由1.0×10〜(-3)Zn(NO_3)_2和4.0×10〜(-3)KOH水溶液,总流速为22.5g / min。将流速提高到较大值的1.5倍,纳米棒具有平均杆宽度的CA.生产了40 nm。

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