PARTIAL MOLAR VOLUMES AT INFINITE DILUTION IN SUPERCRITICAL FLUIDS - PREDICTION WITH CUBIC EQUATIONS OF STATE

机译：超临界流体中无限稀释的局部摩尔体积 - 立方体方程预测

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A comparison among Wong-Sandler, MHV2 and LCVM excess Gibbs free energy mixing rules for Peng-Robinson equation of state is presented for the correlation of partial molar volume at infinite dilution in supercritical fluids. The database employed in this evaluation includes linear, cyclic and aromatic hydrocarbons, alcohols and terpenes. Results show that Wong-Sandler mixing rules are the more accurate in predicting partial molar volume at infinite dilution.

机译：在超临界流体中无限稀释的局部摩尔体积相关的术语中的彭罗宾逊方程的彭罗宾逊方程的超大Gibbs自由能混合规则的比较。该评估中使用的数据库包括线性，环状和芳烃，醇和萜烯。结果表明，黄桑德勒混合规则在无限稀释时预测部分摩尔体积更准确。

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《Italian Conference on Supercritical Fluids and Their Applications》|2004年||共7页
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Silvio A. B. Vieira de Melo; Gloria M. N. Costa; Fernando L. P. Pessoa;
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中图分类 TB126-53;
关键词
Cubic equation of state; GE mixing rules; Supercritical fluid; Partial molar volume; Infinite dilution;

机译：立方式的状态;GE混合规则;超临界流体;局部摩尔体积;无限稀释;

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PARTIAL MOLAR VOLUMES AT INFINITE DILUTION IN SUPERCRITICAL FLUIDS - PREDICTION WITH CUBIC EQUATIONS OF STATE

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